A pin wash is a wash, usually a dark color up to and including black to help define panel lines, recesses, defining area between two parts like a gas cap and hull. I like to apply it over a gloss base so it flows. Unlike a regular wash or filter, I apply a pin wash with a very small brush like a 10/0 by just touching the recessed line, and let the wash work it's way through it. Where it stops I touch it again, and so on.
I give the pin wash a few min to start to dry, then I use a Q-tip dampened, and it's just that, damp with the same thinner you used to make the wash, and I very gently clean off the excess. I do this by brushing the Q-tip across the pin wash. In the example of the gas cap, you just gently work it around, not pushing the Q-tip down into the joint.
Hope my explanation helps.